For citation:
Klimova S. A., Inozemtseva O. A., German S. V., Skosyreva T. S., Peganov A. D. Nanocomposite Langmuir Layers Based on Molecular Brushes. Izvestiya of Saratov University. Physics , 2013, vol. 13, iss. 2, pp. 69-71. DOI: 10.18500/1817-3020-2013-13-2-69-71
Nanocomposite Langmuir Layers Based on Molecular Brushes
The current state of producing of nanostructured composite materials based on polymers like molecular brushes was described. Experimental results established that using hydrophobic nanoparticles allows to effectively integrate the nanoparticles into the brush polymer monolayer with different length of the side chainsIn this case for composite monolayer formation we need to spread an aliquot of the polymer and nanoparticles simultaneously on the surface of the water subphase using Langmuir–Blodgett technique.
- Advincula R. C., Brittain W. J., Caster K. C., Ruhe J. Polymer Brushes. Synthesis, Characterization, Applications. Wiley-VCH ; Verlag GmbH & Co. KGaA, Weinheim, 2004. 471 c.
- Leea H., Pietrasik J., Sheikoc S. S., Matyjaszewskid K. Stimuli-responsive molecular brushes // Progress in Polymer Science. 2010. Vol. 35. P. 24–44.
- Kumar S., Dory Y. L., Lepage M., Zhao Y. SurfaceGrafted Stimuli-Responsive Block Copolymer Brushes for the Thermo-, Photo- and pH-Sensitive Release of Dye Molecules // Macromolecules. 2011. Vol. 44, № 18. P. 7385–7393.
- Арсланов В. В. Полимерные монослои и пленки Ленгмюра–Блоджетт. Влияние химической структуры полимера и внешних условий на формирование и свойства организованных планарных ансамблей // Успехи химии. 1994. Т. 63. С. 3–42.
- Ahrens H., Förster S., Helm C. A. Polyelectrolyte Brushes Grafted to the Air/Water Interface // Macromolecules. 1997. Vol. 30. P. 8447–8452.
- Ahrens H., Papastavrou G., Helm C. A. Characterizing the phases of Langmuir monolayers of cylindrical brushes with x-ray refl ectivity and diffraction // J. Phys. Condens. Matter. 2005. Vol. 17. P. 685–701.
- Luzinov I., Minko S., Tsukruk V. V. Responsive brush layers : from tailored gradients to reversibly assembled Nanoparticles // Soft Matter. 2008. Vol. 4. P. 714–725.
- Currie E. P. K., Norde W., Cohen M. A. Stuart Tethered polymer chains : surface chemistry and their impact on colloidal and surface properties // Advances in Colloid and Interface Science. 2003. Vol. 100–102. P. 205–265.
- Liu Z., Pappacena K., Cerise J., Kim J., Durning C. J., O’Shaughnessy B., Levicky R. Organization of Nanoparticles on Soft Polymer Surfaces // Nano Lett. 2002. Vol. 2, № 3. P. 219–224.
- Zhao B., Zhu L. Mixed Polymer Brush-Grafted Particles : A New Class of Environmentally Responsive Nanostructured Materials // Macromolecules. 2009. Vol. 42, № 24. P. 9369–9383.
- Pyun J. Nanocomposite Materials from Functional Polymers and Magnetic Colloids // Polymer Reviews. 2007. Vol. 47. P. 231–263.
- Jiao Y., Akcora P. Assembly of Polymer-Grafted Magnetic Nanoparticles in Polymer Melts // Macromolecules. 2012. Vol. 45, № 8. P. 3463–3470.
- Stefaniu C., Chanana M., Ahrens H., Wang D., Brezesinski G., Moehwald H. Conformational induced behavior of copolymer-capped magnetite nanoparticles at the air/ water interface // Soft. Matter. 2011. Vol.7. P. 4267–4275.
- Manne S., Aksay I. A. Thin fi lms and nanolaminates incorporating organic/inorganic interfaces // Current Opinion in Solid State & Materials Science. 1997. Vol. 2. P. 358–364.
- Tian Y., Fendler J. H. Langmuir–Blodgett fi lm formation from fluorescence-activated, surfactant-capped, size-selected CdS nanoparticles spread on water surfaces // Chem. Mater. 1996. Vol. 8. P. 969–974.
- Kotov N. A., Zavala G., Fendler J. H. Langmuir–Blodgett fi lms prepared from ferroelectric lead zirconium titanate particles // J. Phys. Chem. 1995. Vol. 99. P. 12375–12378.
- Fendler J. H. Nanoparticles at air/water interfaces // Curr. Opin. Colloid Interface Science. 1996. Vol. 1. P. 202–207.
- Shin H., Collins R. J., De Guire M. R., Heuera A. H., Sukenik C.N. Synthesis and characterization of TiO2 thin fi lms on organic self-assembled monolayers. Part I. Film formation from aqueous solutions // J. Mater. Res. 1995. Vol. 10, iss. 3. P. 692–698.
- Liu Y., Wang A., Claus R. J. Molecular Self-Assembly of TiO2 / Polymer Nanocomposite Films // Phys. Chem. В. 1997. Vol. 101, № 8. P. 1385–1388.
- Minko S. Responsive Polymer Brushes // J. Macromolecular Science. Part C : Polymer Reviews. 2006. Vol. 46. P. 397–420.
- 1371 reads