thermodynamic probability

Derivation of the Thermodynamic Probabilities Using Polynomial Forms

Background and Objectives: A. Einstein suggested at the time that neither the founder of the statistical mechanics L. Boltzmann, nor M. Planck, who has developed the statistical understanding of the entropy of radiation, gave the proper definitions of the thermodynamic probability as a number of equally probable microstates. Meanwhile it was necessary to understand the difference between the Boltzmann’s and Planck’s numbers of microstates.